Bis[μ-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-κO)silver(I)] acetonitrile disolvate
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چکیده
In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hy-drazine ligands and one O atom from a nitrate anion. Inter-molecular N-H⋯O hydrogen bonds link the complex mol-ecules, resulting in a two-dimensional supra-molecular structure parallel to (001).
منابع مشابه
Bis[μ-2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ4 N 2,N 3:N 4,N 5]bis[(nitrato-κO)silver(I)] tetrahydrate
The self-assembly of an angular 2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole ligand (L) with silver nitrate (AgNO3) produced a new dinuclear silver(I) coordination complex, [Ag2(C12H8N4S)2(NO3)2]·4H2O, which crystallizes with two Ag atoms bridged by two L ligands. The Ag atom is surrounded by four N atoms of L and by one O from the nitrate anion defining a distorted square pyramid. The atoms compr...
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